Every Pokemon Center card we price, most valuable first. Prices are what copies actually sold for, updated daily.
What a Pokemon Center card is worth
The most valuable Pokemon Center on this list is Pokemon Center from WoTC Promo at $1,458£1,097€1,284, and the 5 priced copies across 5 sets are worth $1.5k£1.1k€1.3k together. Most of that sits in a handful of printings: the older the set and the scarcer the print run, the wider the gap to the rest.
Pokemon Center is printed in Japanese as well: 3 cards across 3 sets, the most valuable of them Pokemon Center from Expansion Pack (No Rarity) at $7.59£5.71€6.68. Switch the list above to Japanese to read those, or to Both to rank the two catalogues against each other.
The highest PSA 10 on record for Pokemon Center sold for $3,759£2,829€3,310. 1st Edition and reverse holo printings are priced separately from the standard card, because they do not trade at the same money.
If you are trying to identify which Pokemon Center you have, the set name is printed on the card and the collector number sits in the bottom corner. Open the card here and the page carries every printing of it, the graded prices, and whether grading the copy is worth the fee. Sets to start with: WoTC Promo, Base Set (Shadowless), Base Set.